Issue 42, 2005

Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters

Abstract

Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 °C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.

Graphical abstract: Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters

Article information

Article type
Communication
Submitted
20 Jul 2005
Accepted
07 Sep 2005
First published
26 Sep 2005

Chem. Commun., 2005, 5334-5336

Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters

R. Riva, S. Schmeits, F. Stoffelbach, C. Jérôme, R. Jérôme and P. Lecomte, Chem. Commun., 2005, 5334 DOI: 10.1039/B510282K

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