Issue 7, 2006
From the journal:

Chemical Communications

Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds†

Stephan P. Hoffmann,a   Tsuyoshi Kato,a   Fook S. Thama  and  Christopher A. Reed*a  

* Corresponding authors

a Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California 92521, USA
E-mail: chris.reed@ucr.edu
Fax: +1 (951) 827 2027

Abstract

The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2 and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si–H–SiR3+ cations.

Graphical abstract: Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B511344J
Article type
Communication
Submitted
09 Aug 2005
Accepted
01 Dec 2005
First published
05 Jan 2006

Chem. Commun., 2006, 767-769

Permissions

Request permissions

Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

S. P. Hoffmann, T. Kato, F. S. Tham and C. A. Reed, Chem. Commun., 2006, 767 DOI: 10.1039/B511344J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements