Issue 39, 2006

High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

Abstract

The mononuclear Pd(II) complex cis-[PdCl2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.

Graphical abstract: High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

Supplementary files

Article information

Article type
Communication
Submitted
12 May 2006
Accepted
20 Jun 2006
First published
06 Jul 2006

Chem. Commun., 2006, 4081-4083

High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

D. R. Allan, A. J. Blake, D. Huang, T. J. Prior and M. Schröder, Chem. Commun., 2006, 4081 DOI: 10.1039/B606736K

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