Issue 10, 2006
From the journal:

Photochemical & Photobiological Sciences

Cyclometalated iridium(iii)-sensitized titanium dioxide solar cells†

Elizabeth I. Mayo,ab   Kristine Kilså,‡a   Timothy Tirrell,b   Peter I. Djurovich,a   Arnold Tamayo,a   Mark E. Thompson,a   Nathan S. Lewisb  and  Harry B. Grayb  

a Department of Chemistry, University of Southern California, Los Angeles, California

b Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California

Abstract

Ir(III) dyes used as sensitizers in dye-sensitized solar cells produced quantum yields approaching unity for conversion of absorbed photons to current under simulated air mass 1.0 sunlight, with current production resulting from ligand-to-ligand charge-transfer states, rather than the typical metal-to-ligand charge-transfer states in ruthenium-based cells.

Graphical abstract: Cyclometalated iridium(iii)-sensitized titanium dioxide solar cells

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Article information

DOI
https://doi.org/10.1039/B608430C
Article type
Communication
Submitted
14 Jun 2006
Accepted
06 Sep 2006
First published
20 Sep 2006

Photochem. Photobiol. Sci., 2006,5, 871-873

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Cyclometalated iridium(III)-sensitized titanium dioxide solar cells

E. I. Mayo, K. Kilså, T. Tirrell, P. I. Djurovich, A. Tamayo, M. E. Thompson, N. S. Lewis and H. B. Gray, Photochem. Photobiol. Sci., 2006, 5, 871 DOI: 10.1039/B608430C

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