Twelve-connected porous metal–organic frameworks with high H2 adsorption

Junhua Jia; Xiang Lin; Claire Wilson; Alexander J. Blake; Neil R. Champness; Peter Hubberstey; Gavin Walker; Edmund J. Cussen; Martin Schröder

doi:10.1039/B614254K

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Twelve-connected porous metal–organic frameworks with high H₂ adsorption†

Junhua Jia,^a Xiang Lin,^a Claire Wilson,^a Alexander J. Blake,^a Neil R. Champness,*^a Peter Hubberstey,*^a Gavin Walker,^b Edmund J. Cussen^a and Martin Schröder*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, University of Nottingham, University Park, Nottingham, UK

^b School of Mechanical Materials & Manufacturing Engineering, University of Nottingham, University Park, Nottingham, UK
E-mail: m.schroder@nottingham.ac.uk
Fax: +44 (0)115 9513563
Tel: +44 (0)115 9513490

Abstract

The twelve-connected metal–organic frameworks {[Ni₃(OH)(L)₃]·n(solv)}_∞1 and {[Fe₃(O)(L)₃]·n(solv)}_∞2 [LH₂ = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H₂ up to 4.15 wt% at 77 K.

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Article information

DOI: https://doi.org/10.1039/B614254K
Article type: Communication
Submitted: 02 Oct 2006
Accepted: 02 Nov 2006
First published: 07 Dec 2006

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Chem. Commun., 2007, 840-842

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Twelve-connected porous metal–organic frameworks with high H₂ adsorption

J. Jia, X. Lin, C. Wilson, A. J. Blake, N. R. Champness, P. Hubberstey, G. Walker, E. J. Cussen and M. Schröder, Chem. Commun., 2007, 840 DOI: 10.1039/B614254K

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Chemical Communications