Issue 3, 2007
From the journal:

CrystEngComm

Stabilization of the 2D inclined interpenetrated net of {[Co(bpe)(tp)(H2O)2]n by replacement of lattice water molecules with appropriate solvent†

Subal Chandra Manna,a   Ken-ichi Okamoto,b   Ennio Zangrando*c  and  Nirmalendu Ray Chaudhuri*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata, India
E-mail: icnrc@iacs.res.in
Fax: +91 33 2473 2805

b Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305, Japan

c Dipartimento di Scienze Chimiche, University of Trieste, Italy
E-mail: ezangrando@units.it

Abstract

A one-pot reaction of three different components [Co(II), terephthalate dianion (tp) and 1,2-bis(4-pyridyl)ethane (bpe)] in water–methanol (1 : 1) solvent leads to the self assembly of a 2D inclined interpenetrated network of formulation {[Co(bpe)(tp)(H2O)2]·2.5(H2O)}n (1), stabilized as {[Co(bpe)(tp)(H2O)2]·(glycol)}n (2) the reaction being carried out in (1 : 1) water–glycol medium.

Graphical abstract: Stabilization of the 2D inclined interpenetrated net of {[Co(bpe)(tp)(H2O)2]n by replacement of lattice water molecules with appropriate solvent

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Article information

DOI
https://doi.org/10.1039/B617277F
Article type
Communication
Submitted
27 Nov 2006
Accepted
17 Jan 2007
First published
25 Jan 2007

CrystEngComm, 2007,9, 199-202

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Stabilization of the 2D inclined interpenetrated net of {[Co(bpe)(tp)(H2O)2]n by replacement of lattice water molecules with appropriate solvent

S. C. Manna, K. Okamoto, E. Zangrando and N. R. Chaudhuri, CrystEngComm, 2007, 9, 199 DOI: 10.1039/B617277F

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