Issue 12, 2008
From the journal:

Chemical Communications

Synthesis and microwave assisted polymerization of fluorinated 2-phenyl-2-oxazolines: the fastest 2-oxazoline monomer to date†

Matthias Lobert,a   Uwe Köhn,b   Richard Hoogenbooma  and  Ulrich S. Schubert*ab  

* Corresponding authors

a Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology and Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: u.s.schubert@tue.nl

b Laboratory of Organic and Macromolecular Chemistry, Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, Jena, Germany

Abstract

The living cationic ring-opening polymerization of 2-oxazolines with fluorinated aromatic substituents was found to be strongly accelerated by o-fluoro substituents.

Graphical abstract: Synthesis and microwave assisted polymerization of fluorinated 2-phenyl-2-oxazolines: the fastest 2-oxazoline monomer to date

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Article information

DOI
https://doi.org/10.1039/B717455A
Article type
Communication
Submitted
12 Nov 2007
Accepted
17 Dec 2007
First published
25 Jan 2008

Chem. Commun., 2008, 1458-1460

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Synthesis and microwave assisted polymerization of fluorinated 2-phenyl-2-oxazolines: the fastest 2-oxazoline monomer to date

M. Lobert, U. Köhn, R. Hoogenboom and U. S. Schubert, Chem. Commun., 2008, 1458 DOI: 10.1039/B717455A

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