Issue 20, 2008
From the journal:

Dalton Transactions

ScorpoPhos: a novel phosphine-nitrogenligand containing a tris(pyrazolyl)borate ligand core†

Steven Kealey,a   Nicholas J. Long,*a   Philip W. Miller,a   Andrew J. P. Whitea  and  Antony D. Geeab  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: n.long@imperial.ac.uk
Tel: +44 (0)20 7594 5781

b GSK Clinical Imaging Centre, Imperial College London, Hammersmith Hospital, Du Cane Road, London, UK

Abstract

A new tris(pyrazolyl)borate ligand bearing phosphine donor groups appended to the 3-position of the pyrazolyl rings is reported, and the hemilabile behaviour of this tris-N,P ligand in coordination with K+, Tl+ and Cu+ ions is investigated.

Graphical abstract: ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core

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Article information

DOI
https://doi.org/10.1039/B804608P
Article type
Communication
Submitted
17 Mar 2008
Accepted
26 Mar 2008
First published
10 Apr 2008

Dalton Trans., 2008, 2677-2679

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ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core

S. Kealey, N. J. Long, P. W. Miller, A. J. P. White and A. D. Gee, Dalton Trans., 2008, 2677 DOI: 10.1039/B804608P

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