Issue 10, 2008
From the journal:

CrystEngComm

Three-dimensional metal–organic frameworks constructed from bix and 1,2,4-benzenetricarboxylate†

Jing Yao,a   Zhen-Da Lu,a   Yi-Zhi Li,a   Jian-Guo Lin,a   Xian-Ying Duan,a   Song Gao,b   Qing-Jin Meng*a  and  Chang-Sheng Lu*a  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P.R. China
E-mail: mengqj@nju.edu.cn
Fax: +86-25-83314502
Tel: +86-25-83597266

b State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, P. R. China

Abstract

Two new metal–organic complexes [Cd1.5(btrc)(bix)]n (1) and [Zn2(btrc)(Hbtrc)0.5(bix)2]n(2) (H3btrc = 1,2,4-benzenetricarboxylate; bix = 1,4-bis(imidazol-1-ylmethyl)-benzene) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction. Complex 1 represents a three-dimensional (3D) structure based on the 2D sheets and bix pillars. Complex 2 exhibits unique architecture. The two complexes exhibit strong fluorescent emissions in their solid states at room temperature.

Graphical abstract: Three-dimensional metal–organic frameworks constructed from bix and 1,2,4-benzenetricarboxylate

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Article information

DOI
https://doi.org/10.1039/B805263H
Article type
Paper
Submitted
01 Apr 2008
Accepted
20 Jun 2008
First published
23 Jul 2008

CrystEngComm, 2008,10, 1379-1383

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Three-dimensional metal–organic frameworks constructed from bix and 1,2,4-benzenetricarboxylate

J. Yao, Z. Lu, Y. Li, J. Lin, X. Duan, S. Gao, Q. Meng and C. Lu, CrystEngComm, 2008, 10, 1379 DOI: 10.1039/B805263H

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