Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours

Qin-Xiang Jia; Yan-Qin Wang; Qi Yue; Qing-Lun Wang; En-Qing Gao

doi:10.1039/B811865E

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Isomorphous Co^II and Mn^II materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours†

Qin-Xiang Jia,^a Yan-Qin Wang,^a Qi Yue,^a Qing-Lun Wang^b and En-Qing Gao*^a

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* Corresponding authors

^a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, China
E-mail: eqgao@chem.ecnu.edu.cn

^b Department of Chemistry, Nankai University, Tianjin, China

Abstract

Two isomorphous Co^II and Mn^II three-dimensional coordination polymers with tetrazolate-5-carboxylate as magnetic mediator exhibit an unprecedented 3,4-connected self-penetrating net topology; a combination of canted antiferromagnetism and metamagnetism was observed in the Co^II compound, whereas the Mn^II compound shows typical antiferromagnetic behaviors.

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Supplementary files

Crystal structure data TXT (27K)

Article information

DOI: https://doi.org/10.1039/B811865E
Article type: Communication
Submitted: 11 Jul 2008
Accepted: 05 Aug 2008
First published: 22 Sep 2008

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Chem. Commun., 2008, 4894-4896

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Isomorphous Co^II and Mn^II materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours

Q. Jia, Y. Wang, Q. Yue, Q. Wang and E. Gao, Chem. Commun., 2008, 4894 DOI: 10.1039/B811865E

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