Issue 1, 2009

Novel rare case of 2D + 1D = 2D polycatenation Hg(ii) coordination polymer

Abstract

A novel polymeric mercury(II) thiocyanate coordination polymers, [Hg2(µ-bpdh)(µ-SCN)4]n[Hg2(µ-bpdh)(µ-SCN)4]2n (1) (bpdh = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene) was prepared and fully characterized. In compound 1, the bridging ligand bpdh adopts a trans-oid conformation and the network contains two interpenetrating coordination polymers, a 2D net and a 1D double chain, which results in a very rare case of 2D + 1D = 2D polycatenation.

Graphical abstract: Novel rare case of 2D + 1D = 2D polycatenation Hg(ii) coordination polymer

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2008
Accepted
12 Aug 2008
First published
13 Oct 2008

CrystEngComm, 2009,11, 50-51

Novel rare case of 2D + 1D = 2D polycatenation Hg(II) coordination polymer

G. Mahmoudi and A. Morsali, CrystEngComm, 2009, 11, 50 DOI: 10.1039/B813701N

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