Issue 17, 2009

Well-defined hydrocarbon soluble strontium fluoride and chloride complexes of composition [LSr(thf)(μ-F)2Sr(thf)2L] and [LSr(thf)(μ-Cl)2Sr(thf)2L]

Abstract

Reaction of LSrN(SiMe3)2(thf) 1 (L = CH(CMe-2,6-i-Pr2C6H3N)2) with Me3SnF and LAlCl(Me), respectively, gave the first example of a strontium mono fluoride complex [LSr(thf)(μ-F)2Sr(thf)2L]2 and the corresponding chloride derivative [LSr(thf)(μ-Cl)2Sr(thf)2L]3.

Graphical abstract: Well-defined hydrocarbon soluble strontium fluoride and chloride complexes of composition [LSr(thf)(μ-F)2Sr(thf)2L] and [LSr(thf)(μ-Cl)2Sr(thf)2L]

Supplementary files

Article information

Article type
Communication
Submitted
10 Dec 2008
Accepted
17 Feb 2009
First published
11 Mar 2009

Chem. Commun., 2009, 2390-2392

Well-defined hydrocarbon soluble strontium fluoride and chloride complexes of composition [LSr(thf)(μ-F)2Sr(thf)2L] and [LSr(thf)(μ-Cl)2Sr(thf)2L]

S. P. Sarish, H. W. Roesky, M. John, A. Ringe and J. Magull, Chem. Commun., 2009, 2390 DOI: 10.1039/B822148K

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