Issue 37, 2009

Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

Abstract

The iron(II) diaryl FeAr′2 (1) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) reacts cleanly with O2 or CO to afford the monomeric, two-coordinate bis(aryloxide) Fe(OAr′)2 (2) or the η2-acyl–carbonyl complex (η2-Ar′C[double bond, length as m-dash]O)2Fe(CO)2 (3) viaoxygen or CO insertion into the Fe–C bonds; complex 2 has a strictly linear geometry and shows remarkable resistance to O2oxidation.

Graphical abstract: Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2009
Accepted
24 Jul 2009
First published
17 Aug 2009

Chem. Commun., 2009, 5543-5545

Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

C. Ni and P. P. Power, Chem. Commun., 2009, 5543 DOI: 10.1039/B912312A

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