Issue 10, 2010
From the journal:

Chemical Communications

A heterogeneous, selective oxidationcatalyst based on Mn triazacyclononane grafted under reaction conditions†

Nicholas J. Schoenfeldt,a   Andrew W. Korindaa  and  Justin M. Notestein*a  

* Corresponding authors

a Northwestern University, Department of Chemical and Biological Engineering, 2145 Sheridan Rd., Tech. E136, Evanston, USA
E-mail: j-notestein@northwestern.edu
Fax: +1 847 491 3728
Tel: +1 847 491 5357

Abstract

A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7-triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.

Graphical abstract: A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

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Article information

DOI
https://doi.org/10.1039/B920391E
Article type
Communication
Submitted
08 Oct 2009
Accepted
19 Jan 2010
First published
05 Feb 2010

Chem. Commun., 2010,46, 1640-1642

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A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

N. J. Schoenfeldt, A. W. Korinda and J. M. Notestein, Chem. Commun., 2010, 46, 1640 DOI: 10.1039/B920391E

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