The rates of oxygen addition to trans-[IrCl(CO)-(R3P)2](R3P = tertiary phosphine) and the stability of the resulting dioxygen adducts, [O2IrCl(CO)(R3P)2], increase with increasing basicity of the substituent R, provided the substituents have comparable structures; the geometry of R exerts a profound effect on the dynamics of these reactions.
L. Vaska and L. S. Chen, J. Chem. Soc. D, 1971, 1080 DOI: 10.1039/C29710001080
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...