SCHEDULED MAINTENANCE
Decafluoroanthracene undergoes replacement of the 2-fluorine when treated with sodium methoxide or with dimethylamine, and this is not in accord with the amplified Iπ-repulsion theory which requires attack at the 9-position; there is now no theory which rationalizes the position of nucleophilic replacement in all polyfluoro-aromatic compounds.
J. Burdon, A. C. Childs, I. W. Parsons and J. C. Tatlow, J. Chem. Soc., Chem. Commun., 1982, 534 DOI: 10.1039/C39820000534
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