The synthesis of the µ-carbido species of formula (pcFe)2C (pc = phthalocyaninato dianion) has been accomplished by reaction of pcFe with Cl4, while reaction of (pcFe)2C with 1-methylimidazole produces an adduct of formula [(1-Meim)pcFe]2C; on the basis of i.r. and visible spectra and single crystal X-ray data, both species have been characterized as µ-carbido-bridged Fe dimers.
G. Rossi, V. L. Goedken and C. Ercolani, J. Chem. Soc., Chem. Commun., 1988, 46 DOI: 10.1039/C39880000046
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