Issue 11, 1991

A novel type of photosubstitution of [fac-Re(bpy)(CO)3Br](bpy = 2,2′-bipyridine) with P(OR)3 in the presence of triethylamine: efficient formation of [Re(bpy)(CO)2{P(OR)3}2]+Br

Abstract

Photochemical ligand substitution of [fac-Re(bpy)(CO)3Br] with P(OEt)3 in the presence of triethylamine quantitatively gave [Re(bpy)(CO)2{P(OEt)3}3]+Br without the intervention of a mono-substituted product.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 787-788

A novel type of photosubstitution of [fac-Re(bpy)(CO)3Br](bpy = 2,2′-bipyridine) with P(OR)3 in the presence of triethylamine: efficient formation of [Re(bpy)(CO)2{P(OR)3}2]+Br

C. Pac, S. Kaseda, K. Ishii and S. Yanagida, J. Chem. Soc., Chem. Commun., 1991, 787 DOI: 10.1039/C39910000787

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