Issue 59, 2014
From the journal:

RSC Advances

Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative†

Javier A. Cabeza,*a   José M. Fernández-Colinas,a   Pablo García-Álvarez*a  and  Diego Poloa  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica-IUQOEM, Universidad de Oviedo-CSIC, 33071-Oviedo, Spain
E-mail: jac@uniovi.es, pga@uniovi.es

Abstract

Coordinatively unsaturated germylene-bridged diruthenium(0) complexes can be prepared by treating [Ru3(CO)12] with amidinate germylenes of the type Ge(R1bzamR2)(HMDS) [R1bzamR2 = 1-R1-3-R2-benzamidinate, HMDS = N(SiMe3)2], but only when the amidinate contains just one very bulky R group (tBu) (not two).

Graphical abstract: Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

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Article information

DOI
https://doi.org/10.1039/C4RA05972G
Article type
Communication
Submitted
06 May 2014
Accepted
08 Jul 2014
First published
22 Jul 2014

RSC Adv., 2014,4, 31503-31506

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Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

J. A. Cabeza, J. M. Fernández-Colinas, P. García-Álvarez and D. Polo, RSC Adv., 2014, 4, 31503 DOI: 10.1039/C4RA05972G

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