The persistent phosphinyl radical, (H2C)2(NDipp)2P˙, formed upon dissolution from the homolytic cleavage of the P–P bond in the diphosphane [(H2C)2(NDipp)2P]2, was reacted with carbon disulfide, phenyl isocyanate, and phenyl isothiocyanate. The phosphinyl fragments add across the C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
S or CO double bond to give neutral, diamagnetic species.
N. A. Giffin, A. D. Hendsbee and J. D. Masuda, Dalton Trans., 2016, 45, 12636 DOI: 10.1039/C6DT02790C
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