Issue 6, 2022

Unlocking metal coordination of diborylamides through ring constraints

Abstract

A cyclic lithium diborylamide compound was synthesized and crystallographically characterized, revealing strong Li–N bonding in sharp contrast to previous linear diborylamides. Two iron(II) diborylamide complexes were also synthesized, including a 2-coordinate Fe bis(diborylamide) complex. The present cyclic diborylamide represents a new addition to the growing scope of amide ligands.

Graphical abstract: Unlocking metal coordination of diborylamides through ring constraints

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2021
Accepted
15 Dec 2021
First published
16 Dec 2021

Chem. Commun., 2022,58, 867-870

Unlocking metal coordination of diborylamides through ring constraints

W. K. Brown, K. K. Klausmeyer and B. M. Lindley, Chem. Commun., 2022, 58, 867 DOI: 10.1039/D1CC06458D

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