Dimetallic gold(I) and platinum(II) complexes containing a trioxoosmium(VIII) moiety. Crystal structures of [Au(PPh3)(NOsO3)] and cis-[Pt(PMe3)2(NOsO3)2]
Abstract
Reaction of [NBun4][OsO3N] with [Au(PPh3)(CF3SO3)] and cis-[Pt(PMe3)2(CF3SO3)2] afforded the dimetallic complexes [Au(PPh3)(NOsO3)] and cis-[Pt(PMe3)2(NOsO3)2], respectively, which have been characterised by X-ray crystallography.