Issue 40, 2005

Regioselective aromatic C–H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(i) complexes

Abstract

The aromatic C–H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 °C in octane in the presence of a catalytic amount of iridium(I) complexes generated from 1/2[Ir(OMe)(COD)]2 and 2-tert-butyl-1,10-phenanthroline.

Graphical abstract: Regioselective aromatic C–H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(i) complexes

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug 2005
Accepted
01 Sep 2005
First published
21 Sep 2005

Chem. Commun., 2005, 5065-5067

Regioselective aromatic C–H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes

T. Ishiyama, K. Sato, Y. Nishio, T. Saiki and N. Miyaura, Chem. Commun., 2005, 5065 DOI: 10.1039/B511171D

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