Issue 32, 2006

Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

Abstract

The synthesis of three-dimensional (Pm3n) cubic phenylene-bridged hybrid mesoporous silica material using a novel allylorganosilane precursor 1,4-bis(triallylsilyl)phenylene and cetyltrimethylammoniumchloride (C16TMACl) as a structure-directing agent in acidic medium is presented. Sulfonic acid functionalized derivatives of these materials are effective in Friedel–Crafts acylation reactions and in controlling the atmosphere emission of volatile organic compounds, which are responsible for ground level ozone, air toxicity and smog.

Graphical abstract: Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

Article information

Article type
Paper
Submitted
19 May 2006
Accepted
20 Jun 2006
First published
06 Jul 2006

J. Mater. Chem., 2006,16, 3305-3311

Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

M. P. Kapoor, M. Yanagi, Y. Kasama, T. Yokoyama, S. Inagaki, T. Shimada, H. Nanbu and L. R. Juneja, J. Mater. Chem., 2006, 16, 3305 DOI: 10.1039/B607133C

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