Green fabrication of fabric by ethanol/water solvent-mediated self-assembly of homogeneous lignin for oil–water separation

Abstract

The utilization of lignin in material fabrication has garnered significant attention despite its complex structure that greatly limits its applications. This study reports a green method for grading and modifying lignin to prepare stable hydrophobic coatings via the solvent/anti-solvent (ethanol/water) self-assembly method. First, the formic acid lignin particle (FLP) is prepared and the underlying mechanism is primarily ascribed to the hydrogen bonding, π–π interactions among aromatic groups within and between molecules, and hydrophobic interactions. The lignin nanoparticles were utilized to chelate with metal ions (iron) in order to obtain the stable hydrophobic coatings using the special nanostructures of FLP. This hydrophobic coating could be applied to different substrates (blocks, straw, and fabric). The cotton fabric exhibited an initial water contact angle (WCA) that increased from 73.4° to 129.6°, and excellent chemical and physical hydrophobic performance. Moreover, this coating has strong self-cleaning ability and could be used for oil–water separation. In this newly proposed fabrication, ethanol can be recovered in the preparation of lignin nanoparticles, which makes the green and facile preparation of a stable hydrophobic coating possible. Additionally, this work is important in upgrading formic acid lignin by controlling the polarity into value-added hydrophobic materials via green classification.