In dioxane–water mixtures rich in dioxane the hydrolysis of benzoyl fluoride is shown to exhibit two mechanisms of acid catalysis: one at low, and one at high values of [H3O+]; only the second mechanism (A1) is detectable in pure water.
R. E. Motie, D. P. N. Satchell and W. N. Wassef, J. Chem. Soc., Perkin Trans. 2, 1992, 859 DOI: 10.1039/P29920000859
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